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BBGKY hierarchy : ウィキペディア英語版
BBGKY hierarchy
In statistical physics, the BBGKY hierarchy (Bogoliubov–Born–Green–Kirkwood–Yvon hierarchy, sometimes called Bogoliubov hierarchy) is a set of equations describing the dynamics of a system of a large number of interacting particles. The equation for an ''s''-particle distribution function (probability density function) in the BBGKY hierarchy includes the (''s'' + 1)-particle distribution function thus forming a coupled chain of equations. This formal theoretic result is named after Bogoliubov, Born, Green, Kirkwood, and Yvon.
==Formulation==
The evolution of an ''N''-particle system is given by the Liouville equation for the probability density function f_N = f_N(\mathbf_1\dots\mathbf_N, \mathbf_1 \dots \mathbf_N, t) in ''6N'' dimensional phase space (3 space and 3 momentum coordinates per particle)
:
\frac + \sum_^N \dot + \sum_^N \left( - \frac_i} - \sum_^N \frac_i} \right) \frac = 0.

By integration over part of the variables, the Liouville equation can be transformed into a chain of equations where the first equation connects the evolution of one-particle probability density function with the two-particle probability density function, second equation connects the two-particle probability density function with the three-particle probability density function, and generally the ''s''-th equation connects the ''s''-particle probability density function f_s = f_s(\mathbf_1\dots\mathbf_s, \mathbf_1 \dots \mathbf_s, t) with the ''(s+1)''-particle probability density function:
:
\frac + \sum_^s \dot + \sum_^s \left( - \frac_i} - \sum_^s \frac_i} \right) \frac = (N-s) \sum_^s \frac \int \frac_i}\cdot f_ \,d\mathbf_ d\mathbf_.

Here \mathbf_i, \mathbf_i are the coordinates and momentum for ''i''th particle, \Phi^(\mathbf_i) is the external field potential, and \Phi_(\mathbf_i, \mathbf_j) is the pair potential for interaction between particles. The equation above for ''s''-particle distribution function is obtained by integration of the Liouville equation over the variables \mathbf_\dots\mathbf_N, \mathbf_ \dots \mathbf_N.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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